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废弃环氧树脂/聚酰胺复合材料的制备及性能研究

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针对废弃环氧树脂(EP)回收处理困难的问题,将废弃环氧树脂作为填充材料用于聚酰胺66(PA66)的改性.通过熔融挤出的方法制备马来酸酐接枝PA66(PA66-g-MAH)用于增容,得到PA66-g-MAH/EP/PA66复合材料.分别通过万能力学试验机、热重分析仪、扫描电子显微镜等仪器对复合材料进行表征,探究不同相容剂含量对复合材料力学性能、热性能以及微观形貌的影响.结果表明,相容剂的加入可以改善体系的相容性,使复合材料的拉伸强度和弹性模量有一定程度提高;3%PA66-g-MAH/20%EP/PA66复合材料的综合力学性能最好,其拉伸强度为69.2 MPa,弹性模量为678.3 MPa;相容剂加入可以提高复合材料的初始分解温度和最大分解速率所对应温度.
Preparation and properties of waste epoxy resin/polyamide composite materials
To address the difficulty in waste epoxy resin(EP)recycling,EP was used as a filling material for the modifica-tion of polyamide 66(PA66).PA66 grafted with maleic anhydride(PA66-g-MAH)was prepared as a compatibilizer through melt grafting for enhancing the compatibility between PA66 and EP.Then,PA66/EP/PA66-g-MAH com-pounds were prepared through melt extrusion and characterized by using universal mechanical testing machine,thermo-gravimetric analyzer,and scanning electron microscope.The effects of different compatibilizer content on their mechani-cal properties,thermal properties and microscopic morphology were investigated.The addition of PA66-g-MAH en-hanced the compatibility of the compounds,resulting in an increase in the tensile strength and elastic modulus.The PA66/20 wt%EP/3 wt%PA66-g-MAH compound exhibited the optimal comprehensive mechanical performance with tensile strength of 69.2 MPa and an elastic modulus of 678.3 MPa.Moreover,the addition of PA66-g-MAH also in-creased the initial decomposition temperature and the temperature corresponding to the maximum decomposition rate.

waste epoxy resinpolyamide 66maleic anhydride grafted polyamide 66modification

胡棚、徐豪、蔡少君

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江汉大学光电材料与技术学院,武汉 430056

废弃环氧树脂 聚酰胺66 马来酸酐接枝聚酰胺66 改性

2024

中国塑料
中国塑料加工工业协会 轻工业塑料加工应用研究所 北京工商大学

中国塑料

CSTPCD北大核心
影响因子:0.574
ISSN:1001-9278
年,卷(期):2024.38(12)