首页|典型稀土材料催化氧化挥发性有机物研究进展

典型稀土材料催化氧化挥发性有机物研究进展

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挥发性有机物(volatile organic compounds,VOCs)是参与臭氧、二次气溶胶形成的重要前体物,其生物毒性、光化学污染性受到人们的广泛关注,催化氧化是防治VOCs污染的主要技术.稀土材料由于富含表面晶格缺陷、良好的高温稳定性、VOCs亲和力和储释氧能力,在VOCs催化氧化方面受到重点关注.本文就典型稀土材料用于VOCs的热催化、光催化以及光热催化处理开展评述,阐述VOCs的来源、危害和催化氧化机制,探讨不同典型稀土材料的制备方法、结构特征、化学状态用于催化氧化VOCs的效果,明晰了稀土材料的优势并分析了目前面临的难题,以期为稀土材料在VOCs治理中的应用及推广提供参考.
Research Progress of Typical Rare Earth Metals for Catalytic Oxidation of Volatile Organic Compounds
Volatile organic compounds(VOCs)are important precursors involved in the formation of ozone and secondary aerosols,and their biological toxicity and photochemical pollution have received widespread attention.Catalytic oxidation is the main technology for the prevention and control of VOCs pollution.Rare earth materials have attracted attention in the catalytic oxidation of VOCs due to their rich surface lattice defects,good high temperature stability,and excellent oxygen storage/release ability.This article reviews the use of typical rare earth materials for thermal catalysis,photocatalysis,and photothermal catalytic treatment of VOCs,which elabo-rates the sources,hazards,and catalytic oxidation mechanisms of VOCs,discusses the preparation methods,structural characteristics,and chemical states of different typical rare earth materials for catalytic oxidation of VOCs.Moreover,it clarifies the advantages of rare earth materials and analyzes the current problems,in order to provide reference for the application and promotion of rare earth materials in VOCs governance.

rare earth materialsvolatile organic compoundsthermal catalysisphotocatalysisphotothermal catalysis

赵永昌、田时泓、张潇潇、龙璐璐、姚小江

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重庆交通大学河海学院,重庆 400074

中国科学院重庆绿色智能技术研究院大气环境研究中心,中国科学院大学重庆学院资源与环境学院,重庆 400714

稀土材料 挥发性有机物 热催化 光催化 光热催化

国家自然科学基金面上项目重庆市巴渝学者·青年学者项目

22076180YS2020048

2024

中国稀土学报
中国稀土学会 北京有色金属研究总院

中国稀土学报

CSTPCD北大核心
影响因子:1.175
ISSN:1000-4343
年,卷(期):2024.42(3)
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