首页|LiMgPO4∶Tm3+,Er3+磷光体的热释光特性和发光光谱研究

LiMgPO4∶Tm3+,Er3+磷光体的热释光特性和发光光谱研究

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稀土掺杂的橄榄石型磷酸盐LiMgPO4被认为是一种具有优异性能的新型剂量学材料,适用于热释光(TL)测量.使用高温固相反应法合成一种新型的LiMgPO4∶Tm3+,Er3+磷光体.详细研究了 β射线照射 下样品的TL特性、荧光光谱(PL)和热释光三维光谱(TL3D).结果表明,样品在120C和300℃有两个TL发射峰,高温峰的强度明显比低温峰高,这有利于样品TL信号的稳定性.该材料也表现出较强的光释光信号.同时,LiMgPO4∶Tm3+,Er3+磷光粉的TL信号具有良好的可重复性.由TL3D光谱可知,LiMgPO4∶Tm3+,Er3+具有简单的发光峰形,对比Tm单掺磷光体的发光,掺入Er3+使高温峰的强度变强,同时抑制了低温浅陷阱的形成.在0.2~200 Gy的剂量范围内,该材料有很好的线性剂量响应.因此,LiMgPO4∶Tm3+,Er3+磷光体可用于辐射剂量测量.
Thermoluminescence Properties and Luminescence Spectrum of LiMgPO4∶Tm3+,Er3+Phosphor
The rare earth doped olivine phosphate LiMgPO4 is considered as a new dosimetric material with ex-cellent properties for thermoluminescence(TL)measurement.A new LiMgPO4∶Tm3+,Er3+phosphor was synthe-sized by high temperature solid state reaction method.The TL properties,photoluminescence(PL)and thermo-luminescence three-dimensional spectra(TL3D)of the samples under β-ray irradiationwere studied in detail.The results show that there are two TL emission peaks at 120 ℃ and 300 ℃,and the intensity of the high tem-perature peak is significantly higher than that of the low temperature peak,which is conducive to the stability of the TL signal.The material also exhibits a strong luminescent signal.At the same time,the TL signal of LiMgPO4∶Tm3+,Er3+phosphorescent powder has good repeatability.According to TL3D spectrum,LiMgPO4∶Tm3+,Er3+have simple luminescence peak shape.Compared with the luminescence of Tm single-doped phos-phor,the addition of Er3+makes the intensity of high temperature peak stronger and inhibits the formation of low temperature shallow trap.In the dose range of 0.2-200 Gy,the material has a good linear dose response.There-fore,LiMgPO4∶Tm3+,Er3+phosphor can be used for radiation dose measurement.

thermoluminescence(TL)LiMgPO4ErTm

蹇辰茜、梁苑婷、陈媛婷、熊正烨、周冬翠、郭竞渊

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广东海洋大学化学与环境学院,广东湛江 524088

广东海洋大学电子与信息工程学院,广东湛江 524088

热释光 磷酸锂镁

广东省科技计划项目博士启动基金项目广东省教委项目

2015A020216020060302112102S202010266059

2024

中国稀土学报
中国稀土学会 北京有色金属研究总院

中国稀土学报

CSTPCD北大核心
影响因子:1.175
ISSN:1000-4343
年,卷(期):2024.42(4)
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