首页|氢等离子体电弧精炼制备低氧镍镧合金及其应用研究

氢等离子体电弧精炼制备低氧镍镧合金及其应用研究

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采用等离子体熔炼工艺制备低含氧量的Ni-La合金,探究熔炼参数以及La含量对熔炼后合金中氧含量的影响规律.结果表明:等离子气氛中H2的加入更有助于合金的脱氧,熔炼时活性氢等离子体向熔融态金属冲击,与金属中氧杂质接触和反应达到深脱氧的目的.随着H2含量的增加,脱氧速率加快.经过Ar+14%H2氢等离子弧精炼15 min后试样中的氧含量降低至9×10-6,脱氧率达到96.25%.不同初始La含量的Ni-La合金随等离子气氛中H2含量变化趋势一致.将制得的低氧稀土合金加入到CMSX-4合金中制备成稀土单晶合金,对稀土单晶合金进行了 1000 ℃恒温氧化实验.结果表明微量La能有效地提高CMSX-4合金的抗氧化能力.
Preparation of Low Oxygen Nickel Lanthanum Alloy by Hydrogen Plasma Arc Melting and Applied Research
The effects of melting parameters and lanthanum content on the oxygen content of Ni-La alloy prepared by plasma melting were investigated.The results show that the addition of H2 in the melting atmosphere is more conducive to the removal of O of the alloy,and the active hydrogen plasma impinges on the molten metal with the gas molten reactions to achieve the purpose of deep removal of O.The rate of deoxidation increases as the hydrogen content increasing.After the Ar+14%H2 plasma arc refining for 15 min,the oxygen content of the sample decrease to 9 × 10-6,and the deoxidation rate reach 96.25%.The deoxidation rate of Ni-La alloy with different La enhance with the growth of H2 contained in plasma gas.The low oxygen rare earth alloy was added to CMSX-4 alloy to prepare rare earth single crystal alloy.The oxidation experiment of superalloy was carried out at 1000 ℃.The results show that rare earth La can effectively improve the oxidation resistance of CMSX-4 alloy.

nickel lanthanum alloyhydrogen plasma arc meltinglow oxygen contentinoxidizability

吴佳岳、余建波、刘亮、张小新、任忠鸣、王江

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高品质特殊钢冶金与制备国家重点实验室,上海大学材料科学与工程学院,上海 200444

镍镧合金 氢等离子体熔炼 低氧含量 抗氧化性

2024

中国稀土学报
中国稀土学会 北京有色金属研究总院

中国稀土学报

CSTPCD北大核心
影响因子:1.175
ISSN:1000-4343
年,卷(期):2024.42(6)