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真丝织物低甲醛阻燃整理工艺及机理研究

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选用有机磷环保阻燃剂HFPO,配以含氮交联剂2D对真丝织物进行阻燃整理,采用正交试验对阻燃整理工艺进行优化,并考察了阻燃耐久性和阻燃整理对真丝织物游离甲醛及物理机械性能的影响,同时对阻燃机理进行了初步研究.研究结果表明:整理后真丝织物的炭长6.1 cm,极限氧指数高达37%,游离甲醛含量40.02 mg/kg,白度和拉伸强力保留率分别为80.91%和94.06%.对阻燃试样进行热分析和燃烧炭渣表面形貌观察可知,HFPO/2D阻燃体系在凝聚相起阻燃作用,且体系中存在P-N协同效应.
Technology of Low Formaldehyde Flame Retardant Finishing and Mechanism Research on Silk Fabric
In this paper, the organophosphorus environmentally friendly flame retardant HFPO and the nitrogenous crossing-linking agent 2D are applied to treat the silk fabric. The better condition of flame retardancy finishing is optimized through the orthogonal factor method. The flame retardant durability, free formaldehyde content, and physical and mechanical properties are also investigated and the flame-retardant mechanism is preliminarily examined. According to the research results, the carbon length of silk is 5. 7 cm, the limiting oxygen index is 37%, the free formaldehyde content is 40. 02 mg/kg, and the separate retention rates of whiteness and tensile strength are 80. 91% and 94. 06%, respectively. The P-N synergistic effect exists in the HFPO/2D system, which works in the condensed phase. They are examined via thermogravimetric analysis and scanning electronic microscopic photos of silk burning residue.

silk fabriclow formaldehydeflame retardant finishingmechanism research

刘蕊平、沈志斌、包润妍、余志成

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浙江理工大学生态染整技术教育部工程研究中心,杭州310018

浙江理工大学先进纺织材料与制备技术教育部重点实验室,杭州310018

浙江理工大学材料与纺织学院,杭州310018

真丝织物 低甲醛 阻燃整理 机理研究

杭州市经委资助项目

2010-182

2012

浙江理工大学学报
浙江理工大学

浙江理工大学学报

影响因子:0.311
ISSN:1673-3851
年,卷(期):2012.29(6)
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