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猴耳环化学成分研究

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目的:对猴耳环的化学成分进行研究.方法:采用柱色谱分离,通过理化性质、色谱和光谱分析法鉴定化合物的结构.结果:从猴耳环的叶和嫩枝中分离鉴定出一对黄烷异构体7,3′-二-O-没食子酰基特利色黄烷(Ⅰ)和7,4′-二-O-没食子酰基特利色黄烷(Ⅱ),及一个儿茶酚类化合物7-O-没食子酰基表没食子儿茶素(Ⅲ).结论:化合物Ⅰ为新结构,化合物Ⅲ为首次从该属植物中分离得到,且化合物Ⅲ的碳谱数据由本文首次报道.
Studies on the Chemical Comstituents of Pithecellobium clypearia
To study the chemical constituents of Pithecellobium clypearia. Methods: The compounds were isolated from Pithecellobium clypearia with column chromatography. Their structures were characterized on the basis of their physical and chemical preperties, as well as chromatographic and spectroscopic evidences. Results; A pair of isomeric flavans consisting of 7, 3'-O-di-gallyo-ltriceliflavan( Ⅰ ) and 7,4'-O-di-gallyoltricetiflavan( Ⅱ),along with a catechin compound( - )-epigallocatechin-7-O-gallate(Ⅲ) were isolated from the leaves and twigs of Pithecellobium clypearia. Conclusion:Compound Ⅰ is a new flavan. Compound Ⅲ is isolated from Pithecellobium genus for the first time, and its 13C-NMR data is firstly given in the present study.

Pithecellobium clypearia( Jack) Benth.Chemical constituentsIsomeric flavans

苏妙贤、唐之岳、黄伟欢、李药兰、岑颖洲

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香港中文大学,香港

莱泰制药有限公司,广东,广州,510635

暨南大学,广东,广州,510632

猴耳环 化学成分 黄烷异构体

国家自然科学基金国家自然科学基金广东省自然科学基金广东省自然科学基金

20472024207720470401047906025165

2009

中药材
国家食品药品监督管理局,中药材信息中心站

中药材

CSTPCDCSCD北大核心
影响因子:0.913
ISSN:1001-4454
年,卷(期):2009.32(5)
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