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茜素-Al(Ⅲ)络合物制备及对涤纶针织物的染色

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为缩短染色流程,制备茜素-Al(Ⅲ)络合染料,采用紫外-可见和红外光谱对络合物进行表征,分析茜素-Al(Ⅲ)络合染料用于涤纶针织物的染色效果,并与同媒染色工艺对比.结果表明:茜素-Al(Ⅲ)络合染料制备的优化工艺参数为:n(茜素)∶n(Al3+)=2∶1,pH值为5.00,反应温度40 ℃,时间30 min;当染色pH值为3.00时,络合染料染色的黄色谱涤纶织物K/S值增加了81.69%;当染色pH值为9.00时,络合染料染色的红色谱涤纶织物染色K/S值增加了 11.72%;茜素-Al(Ⅲ)络合染料染色涤纶织物的耐干摩擦色牢度3级以上,耐湿摩擦色牢度2~3级以上,耐皂洗变色牢度4~5级.
Preparation of Alizarin Al(Ⅲ)Complex and Its Dyeing on Polyester Knitted Fabric
In order to shorten the dyeing process,alizarin and Al(Ⅲ)complex dyes were prepared and charac-terized by ultraviolet-visible and infrared spectroscopy.The dyeing effects of alizarin and Al(Ⅲ)complex dyes on polyester knitted fabrics were analyzed and compared with the same dyeing process.The results show that the opti-mal process parameters for the preparation of alizarin and Al(Ⅲ)complex dyes are as follows:n(alizarin):n(Al3+)=2:1,pH value 5.00,reaction temperature 40 ℃,and time 30 minutes.When the dyeing pH value is 3.00,the K/S value of yellow spectrum polyester fabric dyed with complex dyes increases by 81.69%.When the dyeing pH value is 9.00,the K/S value of red spectrum polyester fabric dyed with complex dyes increases by 11.72%.Dyeing polyester fabrics with alizarin and Al(Ⅲ)complex dyes has a dry rubbing fastness of more than grade 3,a wet rubbing fastness of more than grade 2~3,and a soaping and fading fastness grade of 4~5.

AlizarinAlizarin Al(Ⅲ)Complex DyeStainingPolyester Knitted Fabric

桑雨蒙、张子琪、欧卫国、张瑞萍

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南通大学纺织服装学院,江苏 南通 226019

南通金仕达高精实业股份有限公司,江苏 南通 226019

茜素 茜素-Al(Ⅲ)络合染料 染色 涤纶针织物

江苏省大学生创新创业训练计划项目(重点项目)

202210304035Z

2024

针织工业
天津市针织技术研究所 中国纺织信息中心

针织工业

北大核心
影响因子:0.262
ISSN:1000-4033
年,卷(期):2024.(1)
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