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针织用聚乳酸纤维可纺性研究及性能分析

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文章旨在比较市面上两种不同聚乳酸切片的可纺性差异,研究分析熔融纺丝前后切片与长丝性能的差异与影响因素.对聚乳酸低弹丝的微观形态、拉伸性能与取向度以及聚乳酸切片的分子量分布、热稳定性能、流变性能进行测试表征.结果表明:由1#切片制得的聚乳酸纤维截面较为致密紧实,具有更高的断裂伸长率、断裂强度、取向度以及结晶度,同时断裂伸长率与断裂强度的CV值较小,产品稳定性高,适合批量生产;纺丝温度较低时,1#切片可纺性更好,2#切片需要设置更高的纺丝温度来提高熔体的可纺性;2#切片的热稳定性能弱于1#切片,纺丝温度大于1#切片,造成热分解程度远大于1#切片,影响产品的机械性能.
Spinnability and Property Analysis of Polylactic Acid Fiber for Knitting
The purpose of this article is to compare the spinnability of two different PLA slices in the market,and the differences and influencing factors of the spinnability of PLA slices and filaments before and after melt spinning are studied.The micromorphology,tensile properties and orientation of Polylactic acid low elastic filament,and the molecular weight distribution,thermal stability and rheological properties of PLA slices are tested and characterized.The results show that the PLA fiber section prepared from 1# is compact,with higher elongation at break,breaking strength,orientation and crystallinity,and smaller CV value,high stability and suitable for mass production.When the spinning temperature is lower,the spinnability of the 1# slice is better,and the spinnability of the 2# slice is improved by setting at a higher spinning temperature.The thermal stability of 2# slices is weaker than that of l#,and the spinning temperature is greater than 1#,resulting in a much higher degree of thermal decomposition than 1#,which affects the mechanical properties of products.

PLA FiberSpinning TechnologySpinnabilityDegradable FiberRheological PropertiesThermal Stability

吕世杰、陈慰来、顾学锋

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浙江理工大学纺织科学与工程学院(国际丝绸学院),浙江杭州 310018

宁波马菲羊纺织科技有限公司,浙江 宁波 315700

聚乳酸纤维 纺丝工艺 可纺性 可降解纤维 流变性能 热稳定性

2024

针织工业
天津市针织技术研究所 中国纺织信息中心

针织工业

北大核心
影响因子:0.262
ISSN:1000-4033
年,卷(期):2024.(3)
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