首页|多尺度纳米纤维结构设计及对铜离子吸附性能

多尺度纳米纤维结构设计及对铜离子吸附性能

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碳纳米纤维及碳纳米管因其超高的比表面积,在重金属离子吸附领域具有广泛的应用前景.文中首先利用静电纺丝工艺制备了聚丙烯腈纳米纤维,对其进行预氧化和炭化后制备了碳纳米纤维,研究了预氧化和炭化工艺对纳米纤维形貌和结构的影响;然后基于等离子体辅助气相沉积工艺在碳纳米纤维表面生长了碳纳米管,探讨了不同功率下纳米纤维表面碳纳米管结构的演化规律;将其用于吸附铜离子污染物,探讨了吸附溶液pH值、金属离子浓度、吸附剂含量等对吸附量的影响规律.
Structural Design of Multi-scale Carbon Nanofibers and Its Adsorption Properties to Copper Ions
Carbon nanofibers and carbon nanotubes have broad application prospects in the field of heavy metal ion adsorption due to their ultra-high specific surface area.In this work,the polyacrylonitrile nanofibers were firstly prepared by electrospinning,and the carbon nanofibers were prepared by preoxidation and carbonization.The effects of preoxidation and carbonization on the morphology and structure of nanofibers were studied.Then,based on the plasma assisted vapor deposition process,the carbon nanotubes were grown on the surface of carbon nanofibers,and the evolution of carbon nanotubes structure on the surface of nanofibers under different power was discussed.They were used to adsorb copper ion pollutants,and the effects of pH value of the adsorption solution,the metal ion concentration,and the adsorbent content on the adsorption capacity were discussed.

Carbon NanofibersCarbon NanotubesElectrostatic SpinningPre-oxidationCarbonizationCop-per IonsAdsorption

郑凯、伍海明、陈娜娜、陈磊

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张家港海关,江苏 苏州 215600

天津工业大学纺织科学与工程学院,天津 300387

碳纳米纤维 碳纳米管 静电纺丝 预氧化 炭化 铜离子 吸附

2024

针织工业
天津市针织技术研究所 中国纺织信息中心

针织工业

北大核心
影响因子:0.262
ISSN:1000-4033
年,卷(期):2024.(11)