针织工业2024,Issue(11) :95-100.

Ni/Co-MOF的制备及对酸性橙156的吸附

Synthesis of Ni/Co-MOF and Its Adsorption Property on Acid Dyes

司俊杰 刘秀明 房宽峻 卢雪
针织工业2024,Issue(11) :95-100.

Ni/Co-MOF的制备及对酸性橙156的吸附

Synthesis of Ni/Co-MOF and Its Adsorption Property on Acid Dyes

司俊杰 1刘秀明 1房宽峻 2卢雪1
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作者信息

  • 1. 天津工业大学纺织科学与工程学院,天津 300387
  • 2. 天津工业大学纺织科学与工程学院,天津 300387;山东生态纺织协同创新中心,山东青岛 266071
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摘要

文章采用溶剂热法制备得到一种新型复合材料Ni/Co-MOF,并对其进行表观形貌、结构表征及对酸性染料吸附性能的研究.结果表明,Ni/Co-MOF具有独特的花瓣状中空纳米笼结构,孔径高达14.56 nm;Ni/Co-MOF对酸性橙156的吸附量最高可达355 mg/g;通过吸附等温线和动力学研究说明酸性橙156在Ni/Co-MOF上的吸附符合Langmuir等温线模型和准二级动力学模型,为吸热自发过程,吸附方式以化学吸附为主;5次吸附与脱附试验后,Ni/Co-MOF仍可对酸性橙156表现出优异的吸附性能.

Abstract

A new type of composite Ni/Co-MOF was prepared by solvo-thermal method,and the surface mor-phology and structure of Ni/Co-MOF were characterized.Then,the absorption property of Ni/Co-MOF for acid dyes was studied.The results show that Ni/Co-MOF has a unique petal-like hollow nano-cage structure,and the pore size is as high as 14.56 nm.The adsorption capacity of Ni/Co-MOF for acid orange 156 was as high as 355 mg/g.Studies on adsorption isotherms and kinetics shows that the adsorption of acid orange 156 on Ni/Co-MOF conform to the Langmuir isotherm model and the quasi-second-order kinetic model,which is an endothermic spontaneous process,and the adsorption method is mainly chemical adsorption.Ni/Co-MOF can still show excellent adsorption performance for adsorbed acid orange 156 after five adsorption-desorption experiments.

关键词

Ni/Co-MOF/酸性橙156/吸附性能/可重复利用

Key words

Ni/Co-MOF/Acid Orange 156/Adsorption Property/Recycling

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出版年

2024
针织工业
天津市针织技术研究所 中国纺织信息中心

针织工业

北大核心
影响因子:0.262
ISSN:1000-4033
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