首页|A new Fe/N doped carbon dot naocatalytic amplification-aptamer SERS/RRS/Abs trimode assay platform for ultratrace Pb2+
A new Fe/N doped carbon dot naocatalytic amplification-aptamer SERS/RRS/Abs trimode assay platform for ultratrace Pb2+
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NSTL
Elsevier
Nanocatalytic amplification of carbon dots is a new way to improve sensitivity. The preparation of the high catalytic activity and stable iron/nitrogen-doped carbon dot (CDBFe) sol and its application in apta-mer (Apt) assay have not been reported yet. In this paper, a simple hydrothermal procedure for the prepa-ration of CDBFe derived from Fe2+-2,2'-bipyridine complex has been developed. It is found that CDBFe has a strong catalytic effect on the indicator reaction of glyoxal (C2H2O2) reduction of HAuCl(4 )to produce gold nanoparticle (AuNP) probe with strong surface enhanced Raman scattering (SERS) at 1617 cm(-1), reso-nance Rayleigh scattering (RRS) effect at 370 nm and absorption (Abs) at 550 nm. A rapid and sensitive CDBFe catalytic amplification Apt method for SERS/RRS/Abs trimode detecting ultratrace lead ions was established, based on the Apt reaction mediated the nanocatalytic indicator reaction. The results show that the SERS intensity and Pb(II) concentration have a good linear relationship in the range of 1.3- 16 pM, and the detection limit is the lowest. In addition, Hg(II) and As(III) can also be measured by this naocatalytic amplification-Apt assay platform. (c) 2022 Elsevier B.V. All rights reserved.
Fe/N doped carbon dotsNanocatalysisAptamerTrimode molecular spectroscopyMetal ion detectionQUANTUM DOTSNITROGENGREENLEADWATERIONSIRON
NSTL
Elsevier
