Chemistry Select2022,Vol.7Issue(46) :5.DOI:doi.org/10.1002/slct.202203659

Microwave-Assisted Tandem Copper-Catalyzed Three-Component Reaction for Synthesis of 2-Iminopyrans

Sivakumar Shanmugam Kamaraj Pasumpon Vaithiyanathan Mahendran
Chemistry Select2022,Vol.7Issue(46) :5.DOI:doi.org/10.1002/slct.202203659

Microwave-Assisted Tandem Copper-Catalyzed Three-Component Reaction for Synthesis of 2-Iminopyrans

Sivakumar Shanmugam 1Kamaraj Pasumpon 1Vaithiyanathan Mahendran1
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作者信息

  • 1. Department of Organic Chemistry,School of Chemistry Madurai Kamaraj University Madurai-625 021
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Abstract

The iminopyrans were synthesized by the CuAAC-MCR approach,the coupling of enaminones,phenyl acetylenes,and sulfonyl,under microwave treatment.The mechanism of the formation of iminopyrans along with amidine has been studied in detail.Experiments to minimize amidine formation were explored,and unfortunately,these experiments were unsuc-cessful.Molar equivalents of enaminones,phenyl acetylenes,and sulfonyl were optimized to increase the yield of iminopyr-an.Fluorescent properties of iminopyrans were characterized using Frontier molecular orbital analysis,UV absorption,and emission studies.

Key words

Click reaction/Cycloaddition reactions/Melamine/Metal-organic framework/Tetrazoles

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出版年

2022
Chemistry Select

Chemistry Select

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