首页|A benzothiazole-based fluorescent and colorimetric probe for the detection of ClO- and its application to zebrafish and water sample

A benzothiazole-based fluorescent and colorimetric probe for the detection of ClO- and its application to zebrafish and water sample

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A benzothiazole-based fluorescent and colorimetric chemosensor BZD ((E)-2-(benzo[d]thiazol-2-yl)-5-((4-(diethylamino)-2-hydroxybenzylidene)amino)phenol) was applied for detecting ClO-. BZD showed fluorescence quenching and color variation for ClO- via oxidative reaction between ClO- and the imine bond. It could effectively detect ClO- over various competitive analytes. Detection limit for ClO- was calculated to be 1.74 mu M by fluorescent method and 16.44 mu M by colorimetric one, respectively. Additionally, BZD could be utilized for sensing ClO- in zebrafish, real water sample and paper strip. The photophysical characteristics and sensing mechanism of BZD to ClO- were studied by fluorescent and UV-visible spectroscopy, NMR titration, and ESI-mass spectrometry. (C) 2021 Elsevier B.V. All rights reserved.

HypochloriteBenzothiazoleChemosensorWater sampleZebrafishTest-stripHYPOCHLOROUS-ACIDRATIOMETRIC DETECTIONSENSORCHEMOSENSORPOLYMERLIGHTCELLRED

Suh, Boeon、Kim, Hyeongjin、Jang, Soogyeong、Kim, Ki-Tae、Kim, Cheal

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SNUT Seoul Natl Univ Sci & Tech

2022

Spectrochimica acta

Spectrochimica acta

ISSN:1386-1425
年,卷(期):2022.270
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