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中国化学快报（英文版）
中国化学快报（英文版）

梁晓天

月刊

1001-8417

cclbj@imm.ac.cn

010-63165638

100050

北京市先农坛街1号

中国化学快报（英文版）/Journal Chinese Chemical LettersCSCDCSTPCD北大核心SCI
查看更多>>本刊是由中国科协主管、中国化学会主办、中国医学科学院药物所承办的学术期刊，是由著名化学家梁晓天院士主编。是中国化学界通向世界的窗口，内容覆盖化学全领域。本刊的办刊宗旨是“新、快、准”，我们将坚持这个宗旨，力求及时反映化学研究中各个相关领域内的最新进展及热点问题，主要读者群是科研人员、研究生、大学教师。现已被国内外多家数据库收录，如SCI　Search、Chemical Abstract、Research Alert、Chemistry Citation Index、《日本科技文献速报》、万方数据数字化期刊群、中国学术期刊过刊全文数据库、中国学术期刊（光盘版）、中国学术期刊文摘、中文期刊全文数据库、俄罗斯Рж期刊源等。
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    ATP-induced supramolecular assembly based on chromophoric organic molecules and metal complexes

    Zhu ShuXin LeiYeye AiKe Shao...
    87-98页
    查看更多>>摘要：Adenosine triphosphate(ATP),known as a common metabolic product in organism,is not only impor-tance to provide energy in various cellular activities but also is widely explored in the bio-inspired syn-thetic supramolecular area which becomes a fascinating topic with the rapid development of biology,chemistry and materials science.In this review,the recent advances about ATP interacted with functional small organic compounds and metal coordinated complexes are summarized.The design principles,its function as an active supramolecular matrix,the associated non-covalent binding modes and assembly induced properties including the optical properties,morphologies are presented in details.Besides,their applications for metal ion detecting,enzyme activity monitoring and drug delivery are described due to their excellently dynamic assembly properties,adjustability,and response to stimuli.Finally,an overview of the existing challenges and future prospects of ATP-induced supramolecular systems are also discussed.
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    Recent advances in remote C(sp3)-H functionalization via chelating group-assisted metal-catalyzed chain-walking reaction

    Jian HanLi-Li ZengQin-Yu FeiYan-Xiang Ge...
    99-110页
    查看更多>>摘要：Aliphatic C(sp3)-H moieties are ubiquitous in numerous organic compounds.Direct functionalization of inert C(sp3)-H bonds is a powerful and straightforward approach for the efficient construction of diverse carbon-carbon or carbon-heteroatom bonds.Chelating group directed metal-catalyzed remote function-alization of readily available alkenes has emerged as an appealing strategy for rapidly accessing various value-added aliphatic molecules.With the aid of directing groups,various α-,β-and y-functionalized alkanes could be synthesized smoothly with excellent regioselectivity.The preferred formation of a sta-ble five-or six-membered metallacycle intermediate terminates the chain-walking at a specific methylene site,which serves as the driving force for excellent site-selective migratory functionalization.This review herein is aimed at summarizing the recent progress on the metal-catalyzed regiodivergent functionaliza-tion of unactivated alkenes by merging alkene isomerization and cross-coupling with the assistance of directing auxiliary.Last but not least,the current situations and future directions in this field are high-lighted and discussed.
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    FDA approved fluorine-containing drugs in 2023

    Qian WangYeping BianGagan DhawanWei Zhang...
    111-122页
    查看更多>>摘要：This review profiles twelve fluorine-containing drugs approved by the US Food and Drug Administration(FDA)for the clinic in 2023.These small molecule drugs represent such therapeutic areas as cancer,neu-romuscular disorder,immunodeficiency,virology,and infectious diseases.Medicinal chemistry discovery,biological activity,and synthetic routes have been discussed for each drug.Also,new trends in structural positioning,functionality,and degree of fluorination are discussed.Besides fluorination,the importance of amino acid residues and chirality in the design of new pharmaceuticals is highlighted.
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    Key progresses of MOE key laboratory of macromolecular synthesis and functionalization in 2023

    Guanxiong YuChengkai XuHuaqiang JuJie Ren...
    123-139页
    查看更多>>摘要：In 2023,The MOE Key Laboratory of Macromolecular Synthesis and Functionalization in Zhejiang Univer-sity had achieved several important results in the five research directions.First,for controllable catalytic polymerization,a new silicon-centered organoboron binary catalyst was developed for copolymerization of epoxides,and a series of cooperative organocatalysts were proposed for ring-opening copolymeriza-tion of chalcogen-rich monomers.Second,with respect to microstructure and rheology,axially encoded metafiber demonstrated its capacity for integrating multiple electronics,while artificial nacre materials showed improved strength and toughness due to interlayer entanglement.Third,concerning separating functional polymers,interfacial polymerization was monitored via aggregation-induced emission,and vac-uum filtration was applied to assist interfacial polymerization.Fourth,in terms of biomedical functional polymers,we designed antibacterial materials such as a novel quaternary ammonium salt that enables polyethylene terephthalate recycling and its antibacterial function,nanozyme-armed phage proved its ef-ficiency in combating bacterial infection,and also transition metal nanoparticles showed capacities in antibacterial treatments.We also made achievements in biomedical materials,including polymeric mi-croneedles for minimally invasive implantation and functionalization of cardiac patches,as well as ROS-responsive/scavenging prodrug/miRNA balloon coating to promote drug delivery efficiency.Besides,meth-ods and mechanisms of RNA labeling has been developed.Fifth,about photo-electro-magnetic functional polymers,through-space conjugation was successfully manipulated by altering subunit packing modes,room-temperature phosphorescent hydrogels were synthesized via polymerization-induced crystallization of dopant molecules,and single crystals of both fullerene and non-fullerene acceptors were grown in crystallized organogel,with their photodetection performance further explored.The related works are reviewed in this paper.
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    Research status and prospect of rechargeable magnesium ion batteries cathode materials

    Runjing XuXin GaoYa ChenXiaodong Chen...
    140-154页
    查看更多>>摘要：Rechargeable magnesium ion batteries(RMBs)are investigated as lithium-ion batteries(LIBs)alternatives owing to their favorable merits of high energy density,abundance and low expenditure of Mg,as well as especially non-toxic safety and low risk of dendrite formation in anodes,which endows them to be more easily assembled in electric-power vehicles for the extended application of civilian-military fields.Never-theless,the high charge density,strong polarization effect,and slow diffusion kinetics of Mg2+remain a large obstacle and thus enormous efforts have to be paid to mend the gap with commercial demand for cathode materials.At present,RMBs cathode materials mainly contain transition metal sulfides/oxides,polyanionic compounds and Prussian blue analogs,and several methods such as nano structuring,dop-ing regulation and coating modification have been applied to materials design for better performance.In this paper,the current research status of RMBs cathode materials at home & abroad is arranged and summarized along with challenges of development in the future focusing on synthesis of RMBs cathode materials with high energy density as well as satisfactory cycling performance.And this analysis aims to provide reference and basis for researchers working on RMBs technology advancement.
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    Metal organic framework modulated nanozymes tailored with their biomedical approaches

    Manoj Kumar SarangiL.D PatelGoutam RathSitansu Sekhar Nanda...
    155-171页
    查看更多>>摘要：Nanozymes are the paradigm for bridging inorganic nanomaterials with biology and environment for tak-ing the spontaneous responsibilities to outplay natural enzymes.Metal-organic frameworks(MOFs)are mesoporous materials of inorganic-organic coordination,bearing ampoules of active/target sites and hav-ing the tendency to mimic natural enzymes.Thus MOF-based nanozymes(NZs)could be recognized for their tremendous potential for bio-catalysis.However,MOFs are of four types namely:modified MOFs,pristine MOFs,MOF-derived materials and MOFs comprised of natural enzymes.The MOFs-based NZ modulated via ultrasound,light,and heat revealed diversified applications.This article is concentrated on different methods for the preparation of MOF-based NZ for mimicking the responses of catalases,multi-functional enzymes,oxidases,superoxide dismutase,hydrolases,and peroxidases,progress and challenges of MOFs/MOF-based materials for exploiting their recent and futuristic approaches in biomedical sector.
      原文链接:
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    Recent advances in copper-based materials for robust lithium polysulfides adsorption and catalytic conversion

    Fengxing LiangYongzheng ZhuNannan WangMeiping Zhu...
    172-181页
    查看更多>>摘要：Lithium-sulfur(Li-S)batteries are considered one of the most promising next-generation secondary bat-teries owing to their ultrahigh theoretical energy density.However,practical applications are hindered by the shuttle effect of soluble lithium polysulfides(LiPSs)and sluggish redox kinetics,which result in low active material utilization and poor cycling stability.Various copper-based materials have been used to inhibit the shuttle effect of LiPSs,owing to the strong anchoring effect caused by the lithio-philic/sulphilic sites and the accelerated conversion kinetics caused by excellent catalytic activity.This study briefly introduces the working principles of Li-S batteries,followed by a summary of the synthetic methods for copper-based materials.Moreover,the recent research progress in the utilization of various copper-based materials in cathodes and separators of Li-S batteries,including copper oxides,copper sul-fides,copper phosphides,copper selenides,copper-based metal-organic frameworks(MOFs),and copper single-atom,are systematically summarized.Subsequently,three strategies to improve the electrochemi-cal performance of copper-based materials through defect engineering,morphology regulation,and syn-ergistic effect of different components are presented.Finally,our perspectives on the future development of copper-based materials are presented,highlighting the major challenges in the rational design and synthesis of high-performance Li-S batteries.
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    Application of metal-organic frameworks to the anode interface in metal batteries

    Ze LiuXiaochen ZhangJinlong LuoYingjian Yu...
    182-202页
    查看更多>>摘要：Metal batteries have attracted considerable attention from researchers because of their low reduction voltage and high specific capacity.However,the reduction in the capacity and lifespan of batteries caused by the dendrite growth of metal anode limits the development of metal batteries.Metal-organic frame-works(MOFs)can be used to protect metal anodes owing to their advantages of ideal specific surface area,tunable porosity,and physiochemical stability in electrolytes.Therefore,MOFs have been exten-sively investigated in metal batteries.The introduction of MOFs to the metal anode interface can greatly improve the performance of batteries.In this review,the synthesis methods of typical MOFs and their derivatives,their protective mechanism on the metal anode,including Li,Na,K,Zn,and Mg,and their ef-fects on the performance of metal batteries were elucidated.This review would help to design and apply MOFs to the anode interface in metal batteries.
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    The strategies to improve TMDs represented by MoS2 electrocatalytic oxygen evolution reaction

    Junan PanXinyi LiuHuachao JiYanwei Zhu...
    203-213页
    查看更多>>摘要：The hydrogen evolution reaction(HER)and the oxygen evolution reaction(OER)are the two half reac-tions that make up the over water splitting reaction.Increasing oxygen evolution reaction rate wound immensely raise the efficiency of over water splitting reaction because it is the rate limiting reaction in water splitting reaction.The key to improve OER performance is the development and utilization of advanced catalysts.As one of the most potential catalysts for HER,it has gradually attracted the atten-tion of researchers in the aspect of catalytic OER.It is very necessary to review the research progress of Transition metal dichalcogenides(TMDs)in catalytic OER to promote the research process in the field.In this review,we comprehensively and systematically summarized the strategies to improve TMDs electro-catalytic OER.First of all,structural regulation of TMDs-based electrocatalyst was summarized in detail,mainly including size engineering,defect engineering,doping engineering,phase engineering and hetero-junction engineering.Once more,magnetic field regulation as a representative of external field regulation to improve TMDs electrocatalytic OER performance was discussed in depth.Last but not least,the strate-gies to improve TMDs electrocatalytic OER is prospected and some views on the development of this field are also put forward,which are expected to enhance the catalytic efficiency of TMDs for OER.
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    The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption:A review

    Jie MaJianxiang WangJianhua YuanXiao Liu...
    214-225页
    查看更多>>摘要：Gas adsorption remains an attractive area of research.The hierarchical structure can reduce diffusion lim-itations and facilitate molecular transport,while acid sites can be used as adsorption sites.These make zeolites widely used in the field of gas adsorption.How to obtain zeolite adsorbents with better ad-sorption properties by modulating the hierarchical structure and acid sites is a pressing issue nowadays.This review highlights the strategies to modulate the hierarchical structure as well as the acid sites;and then explains how these strategies are achieved.The mechanism of zeolite adsorption on gases is then described in terms of these two properties.Lastly,the adsorption properties of zeolites for certain gases under specific conditions are summarised.An outlook of zeolite hierarchical structures and acid site mod-ulation strategies is given.
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