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高等学校化学研究（英文版）
高等学校化学研究（英文版）

唐敖庆

双月刊

1005-9040

cjcu@mail.jlu.edu.cn

0431-88499216

130021

长春市解放大路117号吉林大学北区图书馆414室

高等学校化学研究（英文版）/Journal Chemical Research in Chinese UniversitiesCSCDCSTPCD北大核心SCI
查看更多>>本刊是中华人民共和国教育部委托吉林大学、南开大学主办的化学学科综合性学术刊物，以研究论文、研究快报、研究简报和综合评述等栏目集中报道我国高校和中科院研究所在化学学科及其交叉学科、新兴学科、边缘学科等领域所开展的基础研究，应用研究和重大开发研究所取得的最新成果。
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    Electrocatalytic Performance of Carbon Layer and Spherical Carbon/Carbon Cloth Composites Towards Hydrogen Evolution from the Direct Electrolysis of Bunsen Reaction Product

    ZHANG WanjiaGUO TingyuLIU YanhuaZHANG Xuewei...
    109-118页
    查看更多>>摘要：A composite material comprising a carbon layer and spherical carbon/carbon cloth(C-SC/CC)was fabricated using a hydrothermal-pyrolysis method,employing carbon cloth as the substrate and glucose as the carbon source.The C-SC/CC electrode was evaluated as an electrocatalytic electrode for hydrogen production by electrolysis of Bunsen reaction products.The electrode prepared with 4 g of glucose and annealed at 800 ℃showed excellent electrocatalytic activity.It requires only a potential of 185 mV(vs.SCE)to achieve a current density of 10 mA/cm2.Furthermore,the electrode demonstrated good stability with a 6％loss in current density after 1000 cycles of scanning from 0.2 V to 1.2 V.These results indicate the potential of the SC/CC electrode as an efficient and durable electrocatalyst for the electrolysis of H2SO4 and HI.
      原文链接:
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    • 维普

    Two Indium(Ⅲ)-based Fluorescent Metal-Organic Frameworks for Highly Sensing Fe3+,2,4-DNP,and TNP

    WANG DanLI WenLI GuanghuaHUA Jia...
    119-126页
    查看更多>>摘要：Two novel metal-organic frameworks(MOFs),JLU-MOF130([ln(NH2-BDC)(lmi)(1H-lmi)]-DMF-H20,NH2-H2BDC=2-aminoben-zene-1,4-dicarboxylic acid,1H-lmi=1H-imidazole,DMF=N,N-dimethylformamide)and JLU-MOF131([ln(1,4-NDC)(lmi)(1H-lmi)]-DMF0.5,1,4-H2NDC=1,4-naphthalene-dicarboxylic acid),were synthesized.JLU-MOF130 features a three-dimensional(3D)architecture with a neb topology.JLU-MOF131 is characterized by a two-dimensional(2D)structure with an sql topology.JLU-MOF130 has excellent fluorescence detection performance towards Fe3+,2,4-dinitrophenol(2,4-DNP),and 2,4,6-trinitrophenol(TNP),but the fluorescence detection performance of JLU-MOF131 is further improved by converting NH2-H2BDC to more conjugated 1,4-H2NDC.The Stern-Volmer(SV)quenching constant(Ksv)values of JLU-MOF130 sensing 2,4-DNP,TNP,and Fe3+are 5.24×104,4.44×104,and 4.73x103 L/mol,respectively.The corresponding limit of detection(LOD)values are 1.17,1.36,and 14.59 μmol/L.The Ksv values for JLU-MOF131 are 1.26×105,9.02×104,and 8.48×103 L/mol,and the corresponding LOD values are 0.35,0.42,and 3.60 μmol/L,respectively.Interestingly,the emission wavelengths of the two MOFs obviously shift as the fluorescence emission intensities decrease upon the addition of 2,4-DNP and TNP,which can be applied in selective detection.
      原文链接:
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    Rapid Degrading Carbamazepine in a Novel Advanced Oxidation Process of Bisulfite Activated by Lithium Cobaltate Recovered from Spent Lithium-ion Battery

    YAN JialiYANG KaiyingWANG XiZHAI Jinli...
    127-135页
    查看更多>>摘要：Maximizing the sustainable recycling of spent lithium-ion batteries(LIBs)shows economic and environmental significance.This study recovered lithium cobaltate(LiCoO2,LCO)from spent LIBs cathode powder.The recovered LCO was then combined with NaHSO3 to remove refractory organic pollutants of carbamazepine(CBZ)in water.The degradation of CBZ reached 80.0％within 60 min,by 1O2,S04-·,·OH and 02-·generated in the LCO/NaHSO3 reaction.The electron transfer between Co(Ⅲ)and Co(Ⅱ)was beneficial to the generation of free radicals.The LCO/NaHSO3 degraded CBZ effectively in both secondary outlet water and tap water.However,high concentrations of inorganic ions(Cl-,HCO3-,HPO42-,SO42-,NO3-)and natural organic matter(humic acid,HA)could inhibit the degradation of CBZ.After three cycles,the stability of the LCO/NaHSO3 system was demonstrated by the maintained high efficiency in the degradation of CBZ.The obtained data indicate that the LCO/NaHSO3 system holds great application potential in the field of advanced oxidation degradation of pollutants.
      原文链接:
    • NETL
    • NSTL
    • 万方数据
    • 维普

    A Bird's Eye View of Quantitative Proteome of Tumor Tissues from Lung Cancer Patients by a High Precision Mass Spectrometry Method

    DU XiaohuiLI EnchengWANG QiYOU Xin...
    136-144页
    查看更多>>摘要：Lung cancer produces a high incidence of malignant tumors.There have been many studies on lung cancer using mass spectrometry(MS)technologies.However,most studies have focused on humoral samples.In this work,26 pairs of tissue samples(tumor vs.para-tumor)from patients with lung cancer were analyzed using liquid chromatography-tandem MS(LC-MS/MS)with data-independent acquisition mode.In total,3152 proteins were quantified from tissue samples with high confidence,including 189 up-regulated and 522 down-regulated proteins(tumor vs.para-tumor).In addition,79 and 690 proteins were identified only in para-cancerous samples and cancerous samples,respectively.The results from bio-informatics tools indicated that altered proteins like PEBP1,HRG and LYZ could be ideal reservoirs for screening the potential biomarkers for lung cancer.It is believed these tissue-specific proteomics results will assist in the studies of lung cancer.
      原文链接:
    • NETL
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    Strategy for Detecting Systemic Treatment Sensitivity of Primary Liver Cancer Based on a Novel Infrared-emissive Organic Nanoparticle

    WU JunLI YongzhiQIN HanjiaoGAO Ying...
    145-152页
    查看更多>>摘要：In this study,we synthesized an organic material with near-infrared emission capabilities:4-(2-(4-(9-(4-(diphenylamino)phenyl)naphtho[2,3-c][1,2,5]thiadiazol-4-yl)phenyl)-1H-phenol-1-ylidene)malononitrile(TPA).Furthermore,TPA-PEG2000 fluorescent nanoparticles were prepared via coating the shells with PEG2000.TPA-PEG2000 exhibited strong near-infrared emission near 700 nm,with a photoluminescence quantum yield of 15.09％,indicating a high emission efficiency.Molecular biology experiments have confirmed its low toxicity and excellent biocompatibility.Increased cholesterol and phospholipid levels in liver cancer cell membranes with low sensitivity or high drug resistance lead to increased rigidity,reduced membrane fluidity,reduced endocytic efficiency,and reduced uptake.Therefore,the uptake of TPA-PEG2000 nanoparticles into cells and the near-infrared fluorescence intensity can be used to evaluate the sensitivity of systemic liver cancer treatment in a simple and efficient manner.
      原文链接:
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    Open-vessel Synthesis of Poly-N-methoxyethylglycine

    LIU GuojianMA KeCHEN QiZHANG Donghui...
    153-158页
    查看更多>>摘要：Polypeptoids are widely used in biological applications owing to their diverse functions and proteolytic stability.One type of polypeptoids,poly-N-methoxyethylglycine(P-Nmeg),has been found to possess remarkable hydrophilicity and notable properties in terms of protein,cell,and bacterial antifouling.However,the currently known synthesis methods of P-Nmeg include solid-phase synthesis,which is time-consuming and difficult to scale up,and N-substituted N-carboxyanhydride(NNCA)ring-opening polymerization,whose monomers were difficult to store.In this study,we used the chemical stable Nmeg N-phenoxycarbonyl(NPC)as the monomer,which was obtained without the use of highly toxic reactants,such as phosgene or phosphorus halide,to synthesize P-Nmeg under open-vessel conditions.By adding BnNH2 as an initiator at 80 ℃,we can obtain controllable short chain length P-Nmeg with narrow dispersity.
      原文链接:
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    • 维普

    Chemical Research in Chinese Universities Instructions for Authors

    后插1-后插2页
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    • 维普