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中国化学快报（英文版）
中国化学快报（英文版）

梁晓天

月刊

1001-8417

cclbj@imm.ac.cn

010-63165638

100050

北京市先农坛街1号

中国化学快报（英文版）/Journal Chinese Chemical LettersCSCDCSTPCD北大核心SCI
查看更多>>本刊是由中国科协主管、中国化学会主办、中国医学科学院药物所承办的学术期刊，是由著名化学家梁晓天院士主编。是中国化学界通向世界的窗口，内容覆盖化学全领域。本刊的办刊宗旨是“新、快、准”，我们将坚持这个宗旨，力求及时反映化学研究中各个相关领域内的最新进展及热点问题，主要读者群是科研人员、研究生、大学教师。现已被国内外多家数据库收录，如SCI　Search、Chemical Abstract、Research Alert、Chemistry Citation Index、《日本科技文献速报》、万方数据数字化期刊群、中国学术期刊过刊全文数据库、中国学术期刊（光盘版）、中国学术期刊文摘、中文期刊全文数据库、俄罗斯Рж期刊源等。
正式出版
收录年代

    Selective dissolution for stabilizing solid electrolyte interphase

    Kezhen QiShu-yuan LiuRuchun Li
    1-2页
      原文链接:
    • 万方数据
    • 维普

    Micro/nano flow chemistry by Beyond Limits Manufacturing

    Peiwen LiuFang ZhaoJing ZhangYunpeng Bai...
    3-12页
    查看更多>>摘要：In September 2018,we proposed the cutting-edge concept of"Beyond Limits Manufacturing"(BLM).BLM technology is based on the three-dimensional inner engraving or precise outer engraving of ultra-fast laser,to invent micro/nano scale flow chips or devices,which makes it possible for the microform,inte-gration,economy,safety,high efficiency,green and intelligence of research,development and manufac-turing process,so as to realize transformational manufacturing in the era of Industry 4.0.In this paper,we reviewed the representative results we made in the field of micro/nano flow chemistry during the implementation of the BLM major project(December 2019 to August 2023),and discussed its application prospects in micro/nano flow chemistry.
      原文链接:
    • 万方数据
    • 维普

    Advancements in life-on-a-chip:The impact of"Beyond Limits Manufacturing"technology

    Weiwei HeHongbo ZhangXudong LinLili Zhu...
    13-16页
    查看更多>>摘要：This review explores the concept of life-on-a-chip,which involves the creation of miniaturized biological systems,such as organs,tissues,and model organisms,on microscale platforms called microfluidic chips.These chips consist of intricately etched channels,wells,and chambers that enable precise control and observation of fluids,cells,and biochemical reactions,facilitating the simulation of various aspects of hu-man or animal physiology and the study of responses to different stimuli,drugs,or disease conditions.The review highlights the application of a novel technology,"Beyond Limit Manufacturing"(BLM),in the development of sophisticated three-dimensional cell models and model organism microchips.Model-organism-on-a-chip and organ-on-a-chip(OoC)are among the thriving developments in the field of mi-crofluidics,allowing for the reconstruction of living microenvironments and implementation of multi-ple stimuli.The review discusses the latest advancements in life-on-a-chip technology using BLM and outlines potential future research directions,emphasizing the significant role of these chips in studying complex biological processes in a controlled and scalable manner.
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    Stereochemical editing:Catalytic racemization of secondary alcohols and amines

    Jun ZhangZhiyao ZhengCan Zhu
    17-31页
    查看更多>>摘要：Chiral alcohols and amines are important structural units widely existing in pharmaceuticals,agrochem-icals,and food additives.Dynamic kinetic resolution(DKR)is an efficient strategy to deliver optically active alcohols and amines from their racemates.For the development of DKR method,racemization cat-alyst plays as a crucial element with the requirement of compatibility with the kinetic resolution(KR)system.In this paper,recent advance in the catalytic racemization of secondary alcohols and amines is summarized based on different types of racemizing intermediates,which are redox racemization via ketone/imine intermediates,racemization via radical intermediates,and racemization via carbocation in-termediates.Enzymatic racemization of secondary alcohols and amines is also enclosed.
      原文链接:
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    • 维普

    Molecular recognition of cyclophanes in water

    Fang-Yuan ChenWen-Chao GengKang CaiDong-Sheng Guo...
    32-44页
    查看更多>>摘要：Molecular recognition in water,the biological solvent,always receives significant research focus in supramolecular chemistry.The mechanisms of molecular recognition in water is key to comprehending biological processes at the molecular level.Over the past five decades,supramolecular chemists have developed a vast array of synthetic receptors with highly diverse structures and recognition properties.Among them,cyclophanes represent an important family of macrocyclic receptors that have been ex-tensively explored.The aromatic moieties in cyclophanes not only facilitate chemical modifications to impart water solubility but also enable forming hydrophobic cavities for guest inclusion in aqueous en-vironments.Pioneered by Koga et al.,who reported the first inclusion complex of cyclophanes in water and solid state,numerous water-soluble cyclophanes,including derivatives of blue box,calixarenes,re-sorcinarenes,pillararenes,octopusarenes,biphenarenes,coronarenes,and naphthotubes,etc.,have been synthesized and subjected to investigation of the recognition capabilities in aqueous solutions.This re-view provides an overview of cyclophane receptors designed to bind organic guests in water.We cate-gorize them into two classes based on the modifications made to their hydrophobic cavities:those with"exo-functionalized hydrophobic cavities"and those with"endo-functionalized hydrophobic cavities".We introduce their distinctive features and discuss strategies to enhance recognition affinity and selectivity.This review aims to inspire the development of novel synthetic receptors with intriguing properties and foster practical applications of cyclophanes.
      原文链接:
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    • 维普

    Metal-organic framework and its composites modulate macrophage polarization in the treatment of inflammatory diseases

    Feifei WangHang YaoXinyue WuYijian Tang...
    45-56页
    查看更多>>摘要：Metal-organic framework(MOF)is a periodic sexual network structure with large surface area and high porosity,which is assembled by inorganic nodes and organic ligands through coordinate covalent bond.MOFs have the advantages of controllable pore size and shape,large specific surface area,easy modi-fication and more active sites.In addition,MOF based nanoenzymes display excellent enzyme catalytic activity due to their special structure and multiple exposed metal active sites,controlling the production of reactive oxygen species(ROS)in cells or the body,and thus regulating the polarization of macrophage.This article reviews the mechanism of MOF material regulating macrophage polarization and the function of macrophages with different phenotypes.By utilizing the excellent properties of MOFs and the advan-tages of combining them with bioactive materials,we have discovered their excellent applications in the treatment of inflammatory diseases.Finally,we discussed the current challenges and prospects faced by MOF based composite materials.We expect that the research in this developing field will play a more important role in combating inflammatory diseases in the field of nanomedicine.
      原文链接:
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    • 维普

    Recent progress of MgO-based materials in CO2 adsorption and conversion:Modification methods,reaction condition,and CO2 hydrogenation

    Zixuan ZhuXianjin ShiYongfang RaoYu Huang...
    57-65页
    查看更多>>摘要：Integrated CO2 capture and conversion of(ICCC)is one of the most effective solutions to reduce anthro-pogenic CO2 emissions,which has attracted extensive public attention.Dual functional materials(DFMs),including adsorbent and catalyst,are the key components to achieve ICCC.Magnesium oxide(MgO)is an ideal adsorbent for ICCC,since it is characterized by high theoretical adsorption capacity,low cost,low energy consumption and extensive sources.It can also be used as DFMs in combination with the Ni catalysts.MgO not only can act as an adsorbent in DFMs but also enhance the catalytic performance of Ni.This review summarizes the advantages and modification methods of MgO as adsorbent and the in-fluence of its adsorption conditions on the adsorption performance.Moreover,the important role of MgO in facilitating the catalytic conversion of CO2 is highlighted.Future research focuses are proposed for the development of MgO based DFMs with high adsorption capacity,high stability,conversion,and selectivity as well as low cost and energy consumption.
      原文链接:
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    Unlocking the potential of thin-film composite reverse osmosis membrane performance:Insights from mass transfer modeling

    Kexin YuanYulei LiuHaoran FengYi Liu...
    66-76页
    查看更多>>摘要：Thin-film composite(TFC)reverse osmosis(RO)membranes have attracted considerable attention in wa-ter treatment and desalination processes due to their specific separation advantages.Nevertheless,the trade-off effect between water flux and salt rejection poses huge challenges to further improvement in TFC RO membrane performance.Numerous research works have been dedicated to optimizing membrane fabrication and modification for addressing this issue.In the meantime,several reviews summarized these approaches.However,the existing reviews seldom analyzed these methods from a theoretical perspective and thus failed to offer effective optimization directions for the RO process from the root cause.In this review,we first propose a mass transfer model to facilitate a better understanding of the entire process of how water and solute permeate through RO membranes in detail,namely the migration process out-side the membrane,the dissolution process on the membrane surface,and the diffusion process within the membrane.Thereafter,the water and salt mass transfer behaviors obtained from model deduction are comprehensively analyzed to provide potential guidelines for alleviating the trade-off effect between water flux and salt rejection in the RO process.Finally,inspired by the theoretical analysis and the accu-rate identification of existing bottlenecks,several promising strategies for both regulating RO membranes and optimizing operational conditions are proposed to further exploit the potential of RO membrane per-formance.This review is expected to guide the development of high-performance RO membranes from a mass transfer theory standpoint.
      原文链接:
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    • 维普

    Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination:A mini review

    Xiao-Hong YiChong-Chen Wang
    77-84页
    查看更多>>摘要：Water pollution caused by global population growth,urban expansion and industrialization development is one of the urgent issues that need to be addressed in the 21st century.Up to now,it was challenging for metal-organic frameworks(MOFs)to be used in the actual water treatment due to that the powder MOFs suffered from difficult reuse,poor water stability and easy corrosion.It is an effective strategy to immobilize MOFs powder onto porous sponge foam carriers for accomplishing large flux,facile recycling,easy processing water treatment setups.In this review article,the fabrication approaches and applications of different MOFs/sponge composites were highlighted,in which the fluorescence detection of pollutants,adsorption and separation of pollutants,catalytic reduction and oxidation of pollutants were included.Fi-nally,the future challenges and opportunities of MOF/sponge for water treatment are proposed,aiming to provide in-depth guidance for the future design and manufacture of the immobilized MOFs onto sponge foams.
      原文链接:
    • 万方数据
    • 维普

    Metal-based cathode catalysts for electrocatalytic ORR in microbial fuel cells:A review

    Yaxin SunHuiyu LiShiquan GuoCongju Li...
    85-96页
    查看更多>>摘要：Microbial fuel cells(MFCs)have a simple structure and excellent pollutant treatment and power genera-tion performance.However,the slow kinetics of the oxygen reduction reaction(ORR)at the MFC cathode limit power generation.The electrochemical performance of MFCs can be improved through electrocataly-sis.Thus far,metal-based catalysts have shown astonishing results in the field of electrocatalysis,enabling MFC devices to demonstrate power generation capabilities comparable to those of Pt,thus showing enor-mous potential.This article reviews the research progress of meta-based MFC cathode ORR catalysts,in-cluding the ORR reaction mechanism of MFC,different types of catalysts,and preparation strategies.The catalytic effects of different catalysts in MFC are compared and summarized.Before discussing the prac-tical application and expanded manufacturing of catalysts,we summarize the key challenges that must be addressed when using metal-based catalysts in MFC,with the aim of providing a scientific direction for the future development of advanced materials.
      原文链接:
    • 万方数据
    • 维普